IPC-7526-2007 模板和误印板清洗指南.pdf - 第17页

www.bzfxw.com 1. DI-water only , 2. Aqueous with additives, and 3. Organic solvents. No one product or classes of products are likely to satisfy all cleaning requirements. The cleaning agent must be matched to the soil, …

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be included in the automated program. While not necessar-
ily more effective, an automated system can be more con-
sistent than a semiautomatic system because of reduced
user interface.
Automation itself may be more effective due to the consis-
tent nature of automation. Semiautomated stencil cleaners
rely on an operators selective judgments to determine the
degree of rinsing required to effectively displace the wash
solution and remove residual solderpaste or adhesive resi-
dues from the stencil. Additionally, the operator must deter-
mine how long to subject the stencil to a drying process.
Automation allows all stencils to be subjected to specified
cycle parameters, therefore providing results that are more
consistent.
The wash tank features multiple side-mounted ultrasonic
transducers for thorough paste/adhesive removal. Depend-
ing on the chemistry used, automatic wash-solution filtra-
tion may be required and can be achieved via a built-in fil-
tration pump. Particle waste is captured in a solder paste
tray for fast and easy removal. Some ultrasonic stencil
cleaners use just a solder paste trap while others utilize
only a pump-driven filtration system.
Rinse tank predrained filtration systems are needed to auto-
matically filter rinse water prior to treatment and discharge.
A summary of rinse water treatment: (1) filtered for reuse,
(2) potentially drain disposed, (3) evaporated to atmo-
sphere in standard wastewater evaporation equipment.
Certain cleaning agent characteristics can simplify the
cleaning operation. A ‘no rinse’ chemistry eliminates the
need for a rinse cycle/chamber. Some cleaning chemistries
displace the residue with the soil while not dissolving in
the wash bath. Light residues that float can be removed
from the ultrasonic chamber surface via an overflowing
cascade stream. Heavy residues that sink can be collected
via a trough shaped floor and entrained into a drainage
stream. These streams are continuously cleared of the resi-
due content by filtration or routine maintenance and the
residue free cleaning media is returned to the cleaning
chamber. A no-rinse process should be qualified to assure
that chemical agents remaining on the stencil cause no
effect on future printing or on stencil life (delamination of
the elastomer frame) before use in production.
6.7 Rotating Wand/Fixed Nozzle Spray-In-Air Cleaning
These systems consist of a rotating spray wand, which cre-
ates zones of constantly changing force for improved
cleaning performance. The systems are fully automatic and
do not require transferring the stencil between wash, rinse,
and dry. The systems are PLC control with a wide range of
options.
The systems are designed to use a wide range of engi-
neered cleaning fluids. Aqueous, semiaqueous and solvent
technologies can be selected to remove nonreflowed solder
paste, uncured adhesive, and reflowed flux residues from
stencils and pallets. Solvent systems require flame suppres-
sion systems (or intrinsically safe design). Managing rinse
water and soil load are critical process items that need to
be configured to meet the overall-cleaning requirement.
6.8 Automated Ultrasonic Sponge Stencil Cleaning The
stencil is fixtured into a cleaning cabinet. A stainless steel
tray that holds a sponge is placed over the stencil apertures.
The sponge is wetted with IPA (isopropyl alcohol) or other
compatible solvent. Ultrasonic transducers vibrate the
uncured paste or adhesive into the sponge material. The
waste from the process is accumulated into the sponge. The
sponges are dual hazardous waste due to heavy metal and
solvent content. Fugitive solder balls are commonly rede-
posited onto the stencil surface and require wiping. Wiping
the stencil surface caused solder balls to be redeposited
into the stencil apertures.
6.9 Multifunctional Batch System for Stencils, Boards,
and Maintenance Cleaning
Given the proper chemis-
try(s), many stencil cleaner styles provide multi-
functionality for cleaning stencils, misprints and production
circuit assemblies. In the age of no clean, many assemblers
have eliminated the cleaning process. Multifunctional sys-
tem designs provide a footprint for stencil cleaning, deflux-
ing of populated circuit cards, and cleaning of maintenance
items such as pallets. Many spray or ultrasonic systems
have process variables that are PLC controlled with pro-
grammable process settings. These systems are usually
designed for aqueous engineered cleaning fluids. Filtration
and water management options need to be configured to
meet the process requirement.
7 CLEANING CHEMISTRY OPTIONS
7.1 Cleaning Chemistry Selection
Removal of solder
paste deposits requires a cleaning chemistry that wets, dis-
solves, saponifies, or displaces the flux vehicle. Cleaning
process development hinges on the cleaning chemistry.
Wetting occurs by reducing surface and interfacial tension
by using low surface tension materials that allow the
cleaner to penetrate and undercut the soil-substrate bond.
Dissolution of the flux vehicle allows the metallic spheres
to separate and drop from the aperture. Saponification is
the reaction of free alkalinity that reduces the flux resin
while forming a water-soluble soap. Displacement occurs
by bombarding the contaminant with mechanical force that
facilitates the removal of soil from the tiny apertures. The
cleaning equipment greatly facilitates the cleaning process
and impacts reproducibility. Process variables influencing
cleanliness include cleaning chemistry, concentration, bath
temperature, cleaning time, and mechanical action
imparted by the equipment used.
7.2 Chemistry Choices and the Cleaning Process Sten-
cil cleaning products fall into three broad categories:
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1. DI-water only, 2. Aqueous with additives, and 3. Organic
solvents. No one product or classes of products are likely
to satisfy all cleaning requirements. The cleaning agent
must be matched to the soil, the substrate, the cleaning
requirements, drying requirements, and other performance
and environmental constraints. Inorganic soils are often
referred to as hydrophilic; they dissolve effectively in
water. Organic-based soils, often referred to as hydropho-
bic, tend to dissolve more effectively in organic solvents.
Table 7-1 is a guide for choosing the right cleaning chem-
istry for stencil and/or misprint cleaning applications.
7.3 Solvent Cleaning A hydrocarbon solvent represents
an organic compound containing the elements carbon and
hydrogen. These compounds are primarily from petro-
leum’s, coal tar and plant sources. The principle types of
organic solvents include alcohols, aliphatic petroleum’s,
aromatic hydrocarbons, oxygenated and halogenated sol-
vents, esters and terpenes. A general rule of solvent clean-
ing is ‘like dissolves like,’’ which means that usually non-
polar contaminants are best removed by nonpolar solvents,
while polar or ionic contaminants are best removed by
polar solvents.
7.4 Aqueous Cleaning Aqueous cleaning refers to those
processes in which a substrate is first washed with a water
based cleaning agent, generally followed by a water rinse
(DI or facility water). Water based cleaning agents can be
defined as a combination of water and an additive, usually
organic. These agents are generally combined with some
form of mechanical agitation, such as spray in air, spray
under immersion or ultrasonic that promotes the removal of
the contamination such as solder paste and SMT adhesives.
When cleaning stencils and misprinted electronic assem-
blies, the objective is remove contaminates such as solder
paste, flux residue (one side misprinted the other reflowed
or wave soldered) from the surface of stencil or electronic
assembly. Once the wash step is completed, the parts are
rinsed with water, either DI or facility water, to remove the
cleaning agent and contamination. The parts are then dried,
through either heated air or ambient air in the case of sten-
cils. The quality of the rinse water needed in a cleaning
application depends on the substrate; for example, facilities
water can be sufficient for stencils but is usually not suffi-
cient for electronic assemblies.
Table 7-1 Cleaning Chemistry Selection Guide
Process Nonreflowed Solder Paste/Flux Uncured Adhesive
Manual Stencil Cleaning
Solvent Wipe Solvent Wipe
Aqueous Wipe Aqueous/Solvent Wipe
Stencil Printer Understencil Wipe
Solvent Wipe Solvent Wipe
Aqueous Wipe Aqueous/Solvent Wipe
Aqueous/DI-Water Rinse
Spray Under Immersion
Aqueous
Aqueous/Solvent Mix
Aqueous Surfactant
Aqueous Surfactant
Aqueous/Solvent Mix
Ultrasonic Agitation
Aqueous
Aqueous/Solvent Mix
Aqueous Surfactant
Aqueous Surfactant
Aqueous/Solvent Mix
Spray in Air
Aqueous
Aqueous/Solvent MixAqueous Surfactant
Aqueous/Solvent Mix
Aqueous/No Rinse
Spray Under Immersion
Aqueous Surfactant
Aqueous/Solvent Mix
Aqueous/Solvent Mix
Ultrasonic Agitation
Aqueous Surfactant
Aqueous/Solvent Mix
Aqueous/Solvent Mix
Spray In Air
Aqueous Surfactant
Aqueous/Solvent Mix
Aqueous/Solvent Emulsion
Solvent Cleaning
Spray Under Immersion Solvent Solvent
Ultrasonic Solvent Solvent
Spray in Air Solvent Solvent
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There is a broad array of aqueous cleaning agents. Each
uses inorganic and/or organic mixtures. Most are a combi-
nation of low vapor pressure solvents, surfactants or
saponifiers, and if required, inhibitors. They are designed to
remove polar and nonpolar contamination.
The physical properties do however vary in a number of
ways, the most important being, pH and vapor pressure.
Saponifier/surfactant mixtures usually have a pH around 11
to 13. Certain new formulations have a neutral pH. The
advantage of a pH below 12.5 is user safety and material
compatibility, especially in connection with the stencil. The
advantage of higher pH is the improved effectiveness for
removing flux residues. The other significant differences
for readers to consider are the volatile organic content of
cleaning agent. An inorganic containing cleaning agent has
a low volatile organic content and may therefore qualify
for Clean Air Solvent Certification from districts such as
South Coast Air Quality Management District. However,
some inorganic formulations may not be not sufficient for
adhesive removal, and even in some cases solder paste and
flux residue removal. Furthermore, some inorganic formu-
lations may leave behind white inorganic residues after the
cleaning stage, which may not be as easily removed as an
organic based cleaning agent.
Another issue to consider is bath life. Saponifier formula-
tions have a limited bath life since the components are used
up in the cleaning process. Formulations that are more
modern have a different contamination removal mechanism
and allow the contamination to be largely filtered out.
7.5 Semiaqueous This group of cleaners includes blends
or hybrids with water and organic solvents. Aliphatic, oxy-
genated, ester or terpene solvents are blended with surfac-
tants, builders, stabilizers and inhibitors. Sometimes they
contain water and sometimes they are applied as received
without water, but then are water rinsed. These emulsion
cleaners are used in manual, immersion or coarse spray
applications to saponify, solubilize, emulsify or disperse
soils including grease, oils, wax, adhesives, flux and mis-
print solder pastes where water can be tolerated.
Semiaqueous cleaning refers to a process whereby the sub-
strate is washed in a solvent followed by a rinse with water.
The solvents used in these cleaning agents possess a vari-
ety of characteristics. Many semiaqueous cleaning agents
are formulated to clean a wide range of soils, including
solder pastes and SMD adhesives. They are either soluble
in water or insoluble in water, and all commercially avail-
able semiaqueous cleaning agents are formulated so that
they can be rinsed with water. The cleaning media, along
with agitation, will remove the soils from the stencil sur-
face, and the rinse with water will remove any polar or
ionic soils, as well as residual solvent and undissolved soils
that remain on the surface. Waste management can be com-
plicated because of the creation of both solvent and aque-
ous waste streams.
8 CLEANING PROCESS CONSIDERATIONS
Physics centered on Test identify the chemical aspects of
cleaning; the purely physical mechanisms also play a role.
Generally, the higher the thermal and mechanical energy
applied, the better the cleaning will become. When clean-
ing stencils, thermal energy can affect the adhesive bond
that holds the stencil to the frame.
8.1 Common Rules that Center on Aqueous Cleaning
8.1.1 Temperature
Cleaning effectiveness and speed
improve as temperature increases.
• Temperature generally above 110°F (to be consistent with
clause 3.2) may delaminate adhesive holding stencil to
frame.
• Temperature is typically proportional to cleaning time.
• Reflowed flux resin softens at 140 - 176°F, but can be
cleaned with cleaning agents at ambient up to 120°F.
• A rise in temperature typically reduces the cleaning time.
8.1.2 Energy Higher mechanical action (cavitation or
impingement) improves cleaning.
• Represents one of the greatest variations amongst clean-
ing chemistries as some require heat and some do not. If
the chemistry will clean without heat, additional heating
options may not be required on the cleaning machine
which may lower the equipment cost and save energy.
• High spray pressure, low ultrasonic frequencies and high
ultrasonic power densities could cause stencil and/or mis-
printed PCA damage.
• There needs to be a balance to address compatibility con-
straints.
8.1.3 Solvency/Concentration Higher cleaning agent
concentrations may improve cleaning. However, high con-
centrations may decrease ultrasonic cavitation and reduce
the overall scrubbing action.
• Cleaning fluid should be selected first based on soil com-
patibility.
• Poor solvency for the soil cannot be overcome by using
mechanical force.
• Machine should be integrated with the cleaning fluid.
8.1.4 Time Exposure time to the cleaning agent is
critical.
• Most elastic of the four variables.
• Increase in temperature, energy, and solvency allows a
decrease in time.
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