IPC-7526-2007 模板和误印板清洗指南.pdf - 第22页

www.bzfxw.com solder cleaning process step be reviewed with local POTW of f icials before commencing the discharge of wastewater . Such a review may result in the POTW waiving the need for a permit, or in reducing the mo…

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damage and spray ‘shadowing.’ In addition, the design
must allow for easy loading and unloading of the PCAs
onto the board holder.
9.4 Compatibility Constraints with Cleaning Solutions
Care needs to be taken in the selection of cleaning equip-
ment and chemistries. The very narrow solid areas between
apertures on fine pitch parts could be damaged due to
excessive pressure settings for the wash solution. Addition-
ally, if bristle brushes are used to abrade the residual mate-
rial in apertures the same situation could occur.
Excessive heat in the equipment could cause minor distor-
tion to the stencil resulting in misprints—due to the differ-
ent rates of expansion of the stainless steel foil, polyester
border, and aluminum frame. The epoxy bond could also
come under stress due to heat.
Depending on the cleaning chemistries chosen, there could
be a failure in the fiducials on the stencils. Fiducial fillers
that are not compatible with cleaning chemistries or tem-
perature settings on equipment could release leaving no
method for alignment of the stencil to the boards.
10 ENVIRONMENTAL
Assemblers must consider the effect of the cleaning agent
on air emission, wastewater discharge, and solid waste gen-
eration. Special authorization or permits for air, wastewater
and special handling of solid waste are very often the rule
in those nations that have no precise legal definition of
permitted discharges. The following are most often a con-
cern:
Air
• VOCs (volatile organic compounds)
• Ozone depleting substances
• Global warming substances
• Odors
Wastewater
• Heavy metal cations (notably lead, tin and copper)
• Anions (notably phosphates, nitrites and sulfates)
• Complexing/chelating agents (notably EDTA salts and
ammonium/amine compounds
• PH (acid or base condition)
• COD/BOD
• Toxicity to aqueous life before and after biodegradation
• Other (temperature, solid matter, suspended matter, sur-
face tension modifiers, etc.)
Solid Waste
• Heavy metal cations (notably lead, tin and copper)
• All leachable toxic materials up to 100 years in autho-
rized discharge conditions
• Used solvent
10.1 Air Emissions Air emissions are a concern for some
chemical-cleaning agents used for stencil cleaning opera-
tions. Generally, there are two types of air emissions from
such a cleaning process; (1) VOCs and (2) water vapor.
VOCs are generated from cleaning with organic solvents
and aqueous cleaners that contain organic solvents. In cer-
tain nations and regions, VOCs are highly regulated
because their vapors react with nitrogen oxides (photo-
chemically) producing smog. The water vapor from an
evaporator that is used to concentrate the chemicals from a
wash tank may require an air emission discharge permit. In
any case, it is important to consult with the regulatory
agencies before a cleaning process is installed. Depending
on the particular chemical(s) emitted, the amount of the
chemical(s) emitted and the amount of other chemical
emissions from that facility, the emissions may or may not
be regulated by the State (other regional permitting author-
ity under the Clean Air Act). An air emissions permit may
be needed if the emissions thresholds for a given chemical
or a group of chemicals at that facility is exceeded. The
worldwide trend is toward increasing the stringency of
VOC regulations. However, the definition of what consti-
tutes a VOC varies much from one country or region to
another.
Odors in the workspace and/or odors exhausted to the out-
doors are often a primary concern to maintaining a good
working environment.
10.2 Wastewater The discharge of any wastewater
stream, both by total flow and by chemical make-up must
conform to national, regional and local regulations in all
nations. These may vary from lax to very strict limits with
little flexible conditions. Many nations, particularly in
Europe, have draconian legal requirements dictated on a
national scale, covering many aspects of wastewater qual-
ity. Others have less comprehensive regulations, covering
only the more important considerations. Local authorities
may offer derogations to national legislation where their
local treatment plant is able to handle the otherwise out-of-
tolerance waste. Derogations are frequently accorded to
small users, particularly if it may be shown that the cost of
treating a small quantity of slightly polluting waste would
be out of all proportion to the damage that could be caused.
It must be noted that because an installation is approved in
one place, it may not be elsewhere. In all cases, it is wise
to discuss an installation with the local authorities before
putting it into service, as a polluting fait accompli is never
looked at with a kindly eye.
In the USA, the discharge of the wastewater stream, both
by total flow and by chemical make-up will very likely
require a permit form the local public owned treatment
works (POTW) under the Clean Water Act (CWA). In addi-
tion, such a permit may also require co-current approval
(and in rare cases, regional EPA approval). It is important
that any new or additional wastewater flow from a post
February 2007 IPC-7526
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solder cleaning process step be reviewed with local POTW
officials before commencing the discharge of wastewater.
Such a review may result in the POTW waiving the need
for a permit, or in reducing the monitoring requirements of
a required permit. Superfund regulations place liability on
all drain uses if contaminated sewer sites cannot be linked
to the generator. If using the drain for filtered wastewater
discharge, the user could be held liable for a neighbors
problem and be required to share in the clean-up costs.
Even though there is no universal US EPA rule for elec-
tronics part cleaning, any state can have its own regulations
for these processes. Throughout the USA, these vary
greatly from one regulatory agency to another, from mini-
mal to very strict. Regulatory personnel’s interpretation and
knowledge of this process will determine the difficulty that
one will have with discharging the wastewater. Some local
communities may decide to prohibit a discharge of indus-
trial wastewater. Other communities will follow the state’s
requirements and will rely on the state to monitor the
wastewater for them.
In the past, many nations and regions (states) allowed com-
bining of domestic sewage with industrial wastewater
including heavy metals as long as the final wastewater
complied with the regulations. However, today many of
these cleaning operations are now considered as a point
source discharge. With increasing frequency, regulatory
personnel are taking samples of wastewater from the wash
tank drain and the rinse water drain of the cleaning equip-
ment.
In most European countries and many Asian ones, it is a
legal requirement that the discharge be measured directly
from the machine or the individual wastewater treatment
plant and that dilution of the wastewater stream either from
within the machine or without it, is expressively forbidden.
In other words, if the discharge from the machine does not
conform to the regulations, the water must be purified in
such a way that it does.
One of the more difficult aspects of wastewater treatment is
that of heavy metal cations. Taking the three most impor-
tant ones for electronics cleaning, the known regulations at
the time of this writing may vary from place to place as
follows:
In some nations, the permitted concentration is expressed
in peak milligrams-per-liter, in other, parts-per-million. For
the sake of simplicity, the two units were considered here
as equivalent. Very few regulations in the world permit
integrating/averaging to determine the limit.
In the calculation of this average, those nations with unlim-
ited permitted total in cation concentration were ignored:
this figure is therefore an average of those nations with a
finite limit.
It is evident that removing heavy metals from wastewater
does not destroy these metals. At the best, they are trans-
ported into another form, such as concentrate from mem-
brane treatment or regenerated two bed ion exchangers, as
residues from mixed bed ion exchangers or as a solid pre-
cipitate after hydroxide or ferrite treatment. All these waste
materials are at least as dangerous as the original cations in
the wastewater. They are only displaced. It is a bounden
duty to ensure they are disposed of in as environmentally
friendly manner as possible, no matter the chosen way.
10.3 Solid Waste The disposal of spent or waste-
cleaning chemicals is regulated in most countries as haz-
ardous waste. Spent cleaning chemistries, filter cartridges,
activated carbon or others must be analyzed and character-
ized by someone knowledgeable in hazardous waste gen-
eration, storage and shipment regulations. In the USA, the
federal TCLP (Toxic Characteristic Leachate Procedure)
test is the minimum that must be performed. Applicability
of the hazardous waste rules subject a facility to extensive
regulations on personnel training, storage and handling
requirements and record keeping. Even if hazardous waste
rules are not applicable, local or state rules on solid waste
may apply. Some states offer technical assistance to aid in
this determination. Documentation of test results and
records must be kept to assure the regulatory agency of
compliance with today’s ‘cradle to grave’ requirement.
Complete records of the amount of regulated wastes gener-
ated, transported, and disposed are required.
In addition to analogue regulations, there are very severe
rules in Europe simply for the transport of hazardous waste
and, for that matter, any toxic material. Furthermore, most
regions operate licensed liquid and solid chemical disposal
sites, which are specially constructed to protect the air, sur-
face and ground waters (especially phreatic sites) and the
surrounding soil. Every load of waste must be clearly
labeled as to the nature of the contents. Generally, it is a
wise precaution to make sure that a site can accept a given
waste before despatching it. Combustible waste is usually
incinerated in special kilns. In particular, special licenses
are required to transport waste across a national frontier,
according to the Basel Convention.
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APPENDIX A
Terms and Definitions
Absorbed Contaminant: A contaminant attracted to the
surface of a material that is held captive in the form of a
gas, vapor or condensate.
Adhesive: A substance such as glue or cement used to
fasten objects together. In surface mounting, an epoxy
adhesive is used to adhere SMDs to the substrate.
Adhesive Printing: Stencil printing no longer is limited to
the deposition of solder paste. Stencils may be used to
deposit adhesives on mixed-technology PCA designs in
which the bottom of the board features parts attached with
adhesives for wave soldering.
Aliphatic Solvent: ‘Straight chain’ solvents, derived
from petroleum, of low solvent power.
Alkaline Cleaner: An aqueous engineered composition
that contains alkaline salts. These materials are in a pH
range of 7-14.
Ambient: The surrounding environment coming into con-
tact with the system or component in question. Typically
refers to room temperature processing.
Aperture (Stencil): Openings in the stencil through which
solder paste or adhesive is deposited onto the circuit board.
Aqueous Flux: Water-soluble organic flux.
Aspect Ratio: Aperture width to depth ratio. If the wall
area exceeds the land area, the surface tension of the sol-
der paste will be such that more of the paste will adhere to
the wall, risking a clogging condition.
Azeotropic Cleaning Mixture: A liquid mixture of two or
more solvents that behave like a single solvent. The vapor
pressure by partial evaporation of the liquid has the same
composition as the liquid cleaning chemistry.
Bare Board: An unassembled (unpopulated) printed cir-
cuit board.
Base Solderability: The ease with which a metal or metal
alloy can be wetted by molten solder under minimum real-
istic conditions.
Batch Cleaning Process: The cleaning of multiple parts
or ‘batches of parts’’ as a group where process cycle times
are controlled.
BOD: Biological oxygen demand.
Bridging, Electrical: The unintentional formation of a
conductive path between conductors.
B-Side: The bottom side of a printed circuit assembly.
COD: Chemical oxygen demand.
Cold Hand Cleaning: Manual cleaning using a presatu-
rated wipe or brush that contains a cleaning chemistry that
readily evaporates.
Corrosion: The attack of cleaning chemistry, fluxes, and
flux residues on base metals.
Degradation: A decrease in the performance characteris-
tics or service life of the cleaning chemistry.
Dewetting: A condition that results when molten solder
coats a surface and then recedes to leave irregularly shaped
mounds of solder that are separated by areas that are cov-
ered with a thin film of solder and with the basis metal not
exposed.
Double-Sided Printed Board: A printed board with a
conductive pattern on both of its sides.
Emulsion Cleaning: An aqueous cleaning mixture that
holds immiscible soils, such as adhesive, in suspension.
Feature: The general term that is applied to a physical
portion of a part, such as a surface, hole or slot.
Fine-Pitch Technology: A surface mount assembly tech-
nology with component terminations on less than 0.625mm
(0.025-inch) centers.
Flux: A chemically and physically active compound that,
when heated, promotes the wetting of a base metal surface
by molten solder by removing minor surface oxidation and
other surface films and by protecting the surfaces from
reoxidation during a soldering process.
Flux Activity: The degree or efficiency with which a flux
promotes wetting of a surface with molten solder.
Flux Residue: A flux-related contaminant that is present
on or near the surface of a solder connection.
Hydrophilic: Water loving or having a strong affinity for
water.
Hydrophobic: Water hating or having a strong aversion to
water.
Hydroscopic: Water loving or having a strong affinity to
water.
In-line Cleaning: Parts are processed continuously on a
conveyor with process cycle time being controlled by the
conveyor speed.
Ionic Cleanliness: The degree of surface cleanliness as
measured by the number of ions or weight of ionic matter
per unit square of surface.
Manual Cleaning: A cleaning step where parts are pro-
cessed manually with process cycle time controlled by
operator.
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