IPC-7526-2007 模板和误印板清洗指南.pdf - 第18页

www.bzfxw.com There is a broad array of aqueous cleaning agents. Each uses inorganic and/or organic mixtures. Most are a combi- nation of low vapor pressure solvents, surfactants or saponifiers, and if required, inhibitor…

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1. DI-water only, 2. Aqueous with additives, and 3. Organic
solvents. No one product or classes of products are likely
to satisfy all cleaning requirements. The cleaning agent
must be matched to the soil, the substrate, the cleaning
requirements, drying requirements, and other performance
and environmental constraints. Inorganic soils are often
referred to as hydrophilic; they dissolve effectively in
water. Organic-based soils, often referred to as hydropho-
bic, tend to dissolve more effectively in organic solvents.
Table 7-1 is a guide for choosing the right cleaning chem-
istry for stencil and/or misprint cleaning applications.
7.3 Solvent Cleaning A hydrocarbon solvent represents
an organic compound containing the elements carbon and
hydrogen. These compounds are primarily from petro-
leum’s, coal tar and plant sources. The principle types of
organic solvents include alcohols, aliphatic petroleum’s,
aromatic hydrocarbons, oxygenated and halogenated sol-
vents, esters and terpenes. A general rule of solvent clean-
ing is ‘like dissolves like,’’ which means that usually non-
polar contaminants are best removed by nonpolar solvents,
while polar or ionic contaminants are best removed by
polar solvents.
7.4 Aqueous Cleaning Aqueous cleaning refers to those
processes in which a substrate is first washed with a water
based cleaning agent, generally followed by a water rinse
(DI or facility water). Water based cleaning agents can be
defined as a combination of water and an additive, usually
organic. These agents are generally combined with some
form of mechanical agitation, such as spray in air, spray
under immersion or ultrasonic that promotes the removal of
the contamination such as solder paste and SMT adhesives.
When cleaning stencils and misprinted electronic assem-
blies, the objective is remove contaminates such as solder
paste, flux residue (one side misprinted the other reflowed
or wave soldered) from the surface of stencil or electronic
assembly. Once the wash step is completed, the parts are
rinsed with water, either DI or facility water, to remove the
cleaning agent and contamination. The parts are then dried,
through either heated air or ambient air in the case of sten-
cils. The quality of the rinse water needed in a cleaning
application depends on the substrate; for example, facilities
water can be sufficient for stencils but is usually not suffi-
cient for electronic assemblies.
Table 7-1 Cleaning Chemistry Selection Guide
Process Nonreflowed Solder Paste/Flux Uncured Adhesive
Manual Stencil Cleaning
Solvent Wipe Solvent Wipe
Aqueous Wipe Aqueous/Solvent Wipe
Stencil Printer Understencil Wipe
Solvent Wipe Solvent Wipe
Aqueous Wipe Aqueous/Solvent Wipe
Aqueous/DI-Water Rinse
Spray Under Immersion
Aqueous
Aqueous/Solvent Mix
Aqueous Surfactant
Aqueous Surfactant
Aqueous/Solvent Mix
Ultrasonic Agitation
Aqueous
Aqueous/Solvent Mix
Aqueous Surfactant
Aqueous Surfactant
Aqueous/Solvent Mix
Spray in Air
Aqueous
Aqueous/Solvent MixAqueous Surfactant
Aqueous/Solvent Mix
Aqueous/No Rinse
Spray Under Immersion
Aqueous Surfactant
Aqueous/Solvent Mix
Aqueous/Solvent Mix
Ultrasonic Agitation
Aqueous Surfactant
Aqueous/Solvent Mix
Aqueous/Solvent Mix
Spray In Air
Aqueous Surfactant
Aqueous/Solvent Mix
Aqueous/Solvent Emulsion
Solvent Cleaning
Spray Under Immersion Solvent Solvent
Ultrasonic Solvent Solvent
Spray in Air Solvent Solvent
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There is a broad array of aqueous cleaning agents. Each
uses inorganic and/or organic mixtures. Most are a combi-
nation of low vapor pressure solvents, surfactants or
saponifiers, and if required, inhibitors. They are designed to
remove polar and nonpolar contamination.
The physical properties do however vary in a number of
ways, the most important being, pH and vapor pressure.
Saponifier/surfactant mixtures usually have a pH around 11
to 13. Certain new formulations have a neutral pH. The
advantage of a pH below 12.5 is user safety and material
compatibility, especially in connection with the stencil. The
advantage of higher pH is the improved effectiveness for
removing flux residues. The other significant differences
for readers to consider are the volatile organic content of
cleaning agent. An inorganic containing cleaning agent has
a low volatile organic content and may therefore qualify
for Clean Air Solvent Certification from districts such as
South Coast Air Quality Management District. However,
some inorganic formulations may not be not sufficient for
adhesive removal, and even in some cases solder paste and
flux residue removal. Furthermore, some inorganic formu-
lations may leave behind white inorganic residues after the
cleaning stage, which may not be as easily removed as an
organic based cleaning agent.
Another issue to consider is bath life. Saponifier formula-
tions have a limited bath life since the components are used
up in the cleaning process. Formulations that are more
modern have a different contamination removal mechanism
and allow the contamination to be largely filtered out.
7.5 Semiaqueous This group of cleaners includes blends
or hybrids with water and organic solvents. Aliphatic, oxy-
genated, ester or terpene solvents are blended with surfac-
tants, builders, stabilizers and inhibitors. Sometimes they
contain water and sometimes they are applied as received
without water, but then are water rinsed. These emulsion
cleaners are used in manual, immersion or coarse spray
applications to saponify, solubilize, emulsify or disperse
soils including grease, oils, wax, adhesives, flux and mis-
print solder pastes where water can be tolerated.
Semiaqueous cleaning refers to a process whereby the sub-
strate is washed in a solvent followed by a rinse with water.
The solvents used in these cleaning agents possess a vari-
ety of characteristics. Many semiaqueous cleaning agents
are formulated to clean a wide range of soils, including
solder pastes and SMD adhesives. They are either soluble
in water or insoluble in water, and all commercially avail-
able semiaqueous cleaning agents are formulated so that
they can be rinsed with water. The cleaning media, along
with agitation, will remove the soils from the stencil sur-
face, and the rinse with water will remove any polar or
ionic soils, as well as residual solvent and undissolved soils
that remain on the surface. Waste management can be com-
plicated because of the creation of both solvent and aque-
ous waste streams.
8 CLEANING PROCESS CONSIDERATIONS
Physics centered on Test identify the chemical aspects of
cleaning; the purely physical mechanisms also play a role.
Generally, the higher the thermal and mechanical energy
applied, the better the cleaning will become. When clean-
ing stencils, thermal energy can affect the adhesive bond
that holds the stencil to the frame.
8.1 Common Rules that Center on Aqueous Cleaning
8.1.1 Temperature
Cleaning effectiveness and speed
improve as temperature increases.
• Temperature generally above 110°F (to be consistent with
clause 3.2) may delaminate adhesive holding stencil to
frame.
• Temperature is typically proportional to cleaning time.
• Reflowed flux resin softens at 140 - 176°F, but can be
cleaned with cleaning agents at ambient up to 120°F.
• A rise in temperature typically reduces the cleaning time.
8.1.2 Energy Higher mechanical action (cavitation or
impingement) improves cleaning.
• Represents one of the greatest variations amongst clean-
ing chemistries as some require heat and some do not. If
the chemistry will clean without heat, additional heating
options may not be required on the cleaning machine
which may lower the equipment cost and save energy.
• High spray pressure, low ultrasonic frequencies and high
ultrasonic power densities could cause stencil and/or mis-
printed PCA damage.
• There needs to be a balance to address compatibility con-
straints.
8.1.3 Solvency/Concentration Higher cleaning agent
concentrations may improve cleaning. However, high con-
centrations may decrease ultrasonic cavitation and reduce
the overall scrubbing action.
• Cleaning fluid should be selected first based on soil com-
patibility.
• Poor solvency for the soil cannot be overcome by using
mechanical force.
• Machine should be integrated with the cleaning fluid.
8.1.4 Time Exposure time to the cleaning agent is
critical.
• Most elastic of the four variables.
• Increase in temperature, energy, and solvency allows a
decrease in time.
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• Decrease in temperature, energy, and solvency creates a
need for more time.
• Additional cleaning time may cause moisture absorption
to the stencil adhesive, which could weaken the adhesive
bond interface to the frame and metal etched foil.
8.1.5 Cleanliness Final rinse cleanliness is critical to
part cleanliness.
8.1.5.1 Water Quality and the Cleaning Process When-
ever water is used during the cleaning process, whether for
diluting the chemistry or as rinsewater, DI-water should be
considered to ensure optimal cleanliness.
8.1.5.2 Rinses in the Cleaning Process Although rins-
ing is not always needed, it can be an important step in the
aqueous or semiaqueous cleaning process. Often deionized
or softened water is used, especially in a final rinse stage
to minimize spotting.
Rinsing can be accomplished in many ways. Water spray or
mist can be incorporated directly over a wash tank. This
minimizes product carryover and replaces volume lost due
to evaporation, but may dilute the chemistry concentration
in the tank.
Other types of rinses may include spray-in-air or agitation,
dipping or overflow rinses accomplished in immersion
tanks. Immersion rinses are more prone to contamination
from carryover; therefore, it is not unusual for more than
one rinse stage to be used. In precision cleaning applica-
tions, deionized or reverse osmosis (RO) water is used in
the final rinse where water quality is rigidly maintained
through continuous monitoring of conductivity and/or
refractive index.
8.2 Drying Essentially, there are three common types,
natural, mechanical and evaporative, but many machines
use a combination of them. A third, but less frequently
used, drying method is with use of organic solvents via
displacement or adsorption modes.
When off the printer, stencils are normally cleaned for
inventory and can therefore be allowed to dry naturally.
This conserves energy and frees the stencil cleaner for
additional wash cycles.
There are two ways commonly used for mechanical drying,
centrifugal and high velocity air (air knife). Mechanical
drying, if it is possible, offers the following advantages:
• Low energy requirements
• Rapid and effective
• Removes any residual contaminants in the rinse media
Possible disadvantages of mechanical drying include:
• Heated air used for drying can damage the stencil adhe-
sive in the same manner as heated wash solutions.
• Heated air can cause irregular expansion and contraction
of the stainless steel etched foil, causing distortion of the
etched image.
9 EQUIPMENT ACCESSORIES
9.1 Equipment Accessories
In general, stencil-cleaning
machines include a series of accessories or options that will
enhance the performance and proper operation of the
equipment. These accessories are classified according to
different categories depending on the end use and function:
9.2 Process Control Accessories Depending on the
level of automation and sophistication of the cleaning
equipment, these accessories provide the necessary controls
to achieve proper operation of the cleaning equipment. In
many cases, these accessories include a series of measuring
devices and sensors that are electrically connected to a
central PLC (programmable logic controller) or to a micro-
processor. Functions can be programmed to execute (or
abort) different steps according to the feedback received
from the measuring devices. Typically, the measuring ele-
ments include:
• Temperature sensors.
• Pressure sensors for both air and fluids.
• Resistively/conductivity monitors for tracking ionic con-
tamination and water quality.
• Refractometers to measure the refractive index of aque-
ous solutions to determine the volumetric concentration.
• Timers can be either incorporated within PLC software or
installed as separate devices. Timers provide control of
the different cycle steps such as wash, idle (drag), rinse,
and dry times.
9.3 Operation Accessories These devices ensure proper
and efficient equipment operations. Proper rating and speci-
fication of these must take place in order to guarantee a
safe and effective equipment operation. In general, opera-
tion accessories can be classified as follows (in no particu-
lar order):
9.3.1 Pumps The pumping mechanism is critical to
maintain the desired flow rates, impingement pressures,
and efficient filtration. Pumps are used for wash and rinse
fluid delivery, fluid transfer (i.e., drain), metering proper
concentrations, etc. In general, the performance of the
cleaning operations is directly related to the impingement
pressure delivered by the wash pump onto stencil and PCA
surfaces.
9.3.2 Heaters The heating elements, placed inside the
wash reservoir, heat the fluid to the desired temperature.
The power rating of the heaters should take into account
factors such as the fluid volume, operating temperatures,
heat exchange losses during operation, start-up time, etc.
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