IPC-D-279 EN.pdf - 第84页
prior to removal. Keep the heat away from neighboring components and joints with hot air deflectors and IR shielding panels. E-1.5 Water Vapor Pressure Effects on Plastic Encapsu- lated Components Condensed water vapor at…

Appendix E
Environmental Stresses
The printed board assembly starts its exposure to environ-
mental stresses during bare board fabrication, assembly and
repair/ rework before it even enters the service environ-
ment. These stresses can be thermal, chemical, mechanical
or electrical in nature. It is important to understand the
impact of environmental stresses to assure the reliability of
the assembly during its service life.
E-1.0 THERMAL
E-1.1 Effects of Rework and Repair
‘‘Touch up’’ is the
application of heat and solder to a solder joint which is
deemed cosmetically imperfect. Rework is the correction
of a defect before the SM PWA leaves the plant. Repair is
the correction of a defect found in the field. Information on
rework and repair may be found in IPC-R-700. Each cor-
rection requires the heating of one or more solder joints
above the liquidus temperature of lead-tin eutectic solder
(183°C), typically above 210°C, and may involve the
removal and replacement of a component. Note that this
temperature of 183°C is well above several critical tem-
peratures in a SM PWA.
E-1.2 Glass Transition Temperature for Printed Boards
The glass transition temperature (T
g
) of most epoxy-glass
boards is ~125°C. For multi-functional epoxy glass boards,
T
g
is ~160°C. T
g
is greater for polyimide glass printed
boards which have a T
g
of 250°C. There are many other
printed board materials that fall between these two
extremes. Exceeding the T
g
of the printed board results in
significant expansion of the printed board in the z axis,
hence in stresses in the barrels of plated through holes and
vias; the result can be intermittent or permanent opens. The
intermittent opens can generally be detected during tem-
perature changes of the PWA (see Appendix B).
Printed boards with a lower T
g
such as epoxy-glass boards
when heated locally, during component removal or compo-
nent replacement, to temperatures > T
g
, will tend to bulge
in the heated area. The solder joints of the replacement
component will be under tension and may fail when the
assembly cools down.
When using hot gas or IR systems to remove or replace
components, minimize printed board time at temperature.
During component removal, there should be no component
lifting or twisting during removal until solder is liquid on
all lands. This minimizes stress on the leads where they
enter the component package (with the result of cracked
plastic package body, damaged glass to metal seals), as
well as stress on the lands and their adhesive bond to the
printed board (with the result of lifted lands).
E-1.3 Intermetallic Compound Growth The copper in
the printed board conductors and component leads reacts
more rapidly with the tin in the solder to form a brittle
intermetallic compound (IMC) such as Cu
3
Sn and Cu
6
Sn
5
at higher temperatures. The original eutectic solder will be
transformed into a lead-rich layer. In the worst case, the
surface is exposed and oxidized; this lead oxide rendering
that surface unsolderable.
A solder joint kept at temperatures exceeding 150°C will
result in a lead-rich joint which is less ductile than one with
eutectic solder and the fatigue life of the joint will be
degraded. The IMC layer will tend to act as a shear plane
under overload conditions. These comments apply to
neighboring joints during component removal or replace-
ment and to ‘‘touch up’’ of a joint; some data indicate that
solder joints which undergo a ‘‘touch up’’ are less reliable.
If the molten lead is removed from the land by wiping, the
exposed IMC layers can rapidly oxidize and become unsol-
derable.
If the heat source is solder (wave or fountain), the interme-
tallics will be carried away and in the extreme, the copper
land will be dissolved.
When using hot gas or IR systems to remove or replace
components, keep the heat away from neighboring compo-
nents and joints. Hot air deflectors and IR shielding panels
may be required for component protection.
E-1.4 Glass Transition Temperature for Plastic Encap-
sulating
The T
g
range of most molding compounds used
in the plastic encapsulation of semiconductors and passive
networks is in the range of ~150°C to 180°C.
Exceeding the T
g
of the moulding compound of the com-
ponents during component removal results in internal
stresses to the metallization and passivation of the silicon
chip. This damage can hinder failure analysis of the
removed component and can also be suffered by a neigh-
boring component. Disruption of the metallization can
result in opens and dysfunction of the chip. Damage to the
passivation can result in long term corrosion of and opens
in the metal. Exceeding the T
g
can also cause delamination
of the molding compound from the surface of the silicon
chip or the surfaces of the leadframe; condensed moisture
can pool in the delaminated sites and lead to dendrites and
corrosion. Where the delamination coincides with bonding
pads and wire bonds, bond shear can occur.
When using hot gas or IR systems to remove or replace
components, if subsequent failure analysis is to be per-
formed on the removed component, dry the component
IPC-D-279 July 1996
72

prior to removal. Keep the heat away from neighboring
components and joints with hot air deflectors and IR
shielding panels.
E-1.5 Water Vapor Pressure Effects on Plastic Encapsu-
lated Components
Condensed water vapor at the inter-
faces within a plastic encapsulated surface mount compo-
nent (PSMC) rapidly turns into steam and can cause
delamination between the moulding compound and various
elements such as the leadframe, the bonding fingers, or the
chip/die surface. This phenomenon normally occurs at
~220°C. In extremely susceptible components, the thresh-
old temperature is expected to be lower than 220°C. In the
worst case the delamination of the molding compound can
progress to a continuous crack between the die and the
exterior surface of the package, permitting materials such
as flux and cleaning solvents to enter the package.
These materials, in the presence of water, corrode the met-
allization of the die; in the additional presence of DC bias,
dendrites can form between conductors. Even when there
are no external cracks, ionizable substances can be
extracted from the moulding compound or from the surface
of the chip (such as from phosphorous doped oxide); these
materials, together with condensed water are trapped in the
delaminated regions and, over time, result in corrosion and
dendrites (see Appendix C).
When using hot gas or IR systems to remove or replace
components, particularly if subsequent failure analysis is to
be performed on the removed component, dry the compo-
nent prior to removal. Hot air deflectors and IR shielding
keep the heat away from the neighboring components and
joints. Where hot gas or IR has been used to remove a
component and the body temperature has exceeded ~260°C
for 10 seconds, the re-use of that component is not advised,
particularly if the component is susceptible to plastic pack-
age cracking and has not been dried out prior to removal.
Characterize replacement parts for plastic package cracking
susceptibility by the procedures in IPC-SM-786 or IPC-
TM-650, method 2.6.20.
E-1.6 Water Vapor Pressure Effects on Printed
Boards
The glass-epoxy or glass-polymer interface can
separate or delaminate, resulting in ‘‘measling’’ when
heated above ~260°C for extended periods. This phenom-
ena occurs at the 260°C temperature for glass epoxy boards
and lower temperature in glass polyimide boards that have
been exposed to moist environments. Conductive anodic
filaments (CAF) can form low or high resistance conduc-
tive paths between the barrels of the PTVs (vias) or PTHs
(plated-through-holes) where the measling has occurred.
Most glass-polymer printed board materials should have
been evaluated at 260°C for measling during the ‘‘solder
float test.’’ Increased susceptibility to measling or delami-
nation is noted when the polymer has a significant moisture
content; polyimide or polyimide based substrates should be
dried prior to high temperature exposure.
When using hot gas, IR, or manual iron systems to remove
or replace components, oven dry the substrate at 125°C for
24 hours prior to high temperature exposure and minimize
printed board time at temperature. Use thermometry to
measure and control the temperature of the substrate and
the component during removal and replacement; gas stream
temperatures > 350°C have been noted in systems setup for
rapid component removal.
E-1.7 Solder Melt Temperature Effects At the tempera-
tures required to melt solder, the adhesive binding the cop-
per conductor to the printed board weakens. Aggressive use
of a soldering iron to move or remove solder or to move a
component lead by lifting, prodding or twisting before the
solder is completely melted can result in the bending, tear-
ing or complete failure of both external and internal lands
or conductors; conductor repair is then necessary. The same
land or conductor damage follows premature lifting or
twisting of a component prior to complete solder melting.
During component removal and rework/replacement, such
as on connectors and PGAs with fountain solder, minimize
the exposure of the printed board to the molten solder.
Alternatives are to employ thicker copper plating or nickel
barrier plating to minimize the effects of copper dissolu-
tion, particularly on the PTH or PTV knees.
E-1.8 Temperature Excursion (T) and Temperature
Rate of Change (T/t)
If molten solder contacts the ter-
mination of a multilayer ceramic capacitor (MLCC), mul-
tilayer ceramic inductor, or multilayer ceramic filter net-
work, during ‘‘touch up’’, rework or repair, and results in a
thermal transient exceeding 4°C/second, a crack may
result. The crack occurs in the ceramic body under the ter-
mination, hidden from visual inspection but capable of
being a site for dendriting under conditions of moisture and
bias. Most MLCC suppliers recommend a ∆T < 100°C.
Some soldering irons, set at 425°C, with sufficient thermal
mass in the tip, and with a tip wet with solder will transfer
heat so rapidly that the ceramic under the termination will
crack. Preheating of the component above 150°C may be
required to avoid this kind of cracking but may result in
damage to other components or the printed board. The
issue of thermal shock cracking for MLCCs is worse for
capacitors with high values and high thickness; other
parameters which correspond to thermal shock susceptibil-
ity are high layer count, high dielectric constant or low
working voltage rating. Require your component supplier
to provide data regarding the ∆T and ∆T/∆t to which the
particular capacitor (dielectric type, value, working voltage
case style, temperature coefficient of capacitance) is robust;
this data may restrict your choice of component values
(parameters) or suppliers.
July 1996 IPC-D-279
73

E-2.0 CHEMICAL
E-2.1 PWA Cleanliness
Where water soluble or other
fluxes are used, assure that the PWA is cleaned at least to
the ionic contamination levels expected of a first-pass
board. Otherwise, long term failure mechanisms may
result. Corrosion stress cracking of the solder joints may
occur, together with dendrites on the surface of the printed
board and loss of Surface Insulation Resistance perfor-
mance (particularly important in high impedance linear
applications). See also the comments on cleaning under
‘‘Conformal Coating’’.
E-3.0 MECHANICAL
E-3.1 PWA Flexure
Excessive flexure of the PWA due to
shock, vibration or handling during rework or repair can
result in a cracked component body, a detached termina-
tion, or an overloaded and failed solder joint.
E-3.2 Tooling Impact Impact of a hard tool on a ceramic
component body or termination can result in a cracked or
fractured component body.
During component removal, there should be no mechanical
stress on neighboring components. Some removal tech-
niques and tools have been observed to use a neighboring
component as a pivot or fulcrum.
E-4.0 ELECTRICAL
E-4.1 Electrostatic Discharge (ESD)
Observe ESD pre-
cautions while handling, testing, and transporting the PWA
to avoid the introduction of infant and latent defects.
E-5.0 SMT FAILURES/STRESS CONDITIONS
E-5.1 Component Derating Reference Conditions
Component derating is commonly referenced to the abso-
lute maximum ratings defined by the manufacturer’s speci-
fication or data sheet. Each of the several maximum ratings
(e.g. power, voltage, current, temperature) must be applied
individually and not in combination with any other abso-
lute maximum rating. Where experience dictates, more
conservative references may be used.
E-5.2 The Most Important Stress and Some Precau-
tions
The most universal stress is temperature. The criti-
cal point at which to evaluate temperature is the active site
or junction or film, not the ambient temperature; this defi-
nition of the critical temperature takes into account the
temperature rise in the component due to heat generated
within the component. Many of the common failure
mechanisms in electronic components double their failure
rate contribution with an increase of only 10°C.
Caution The absolute maximum ratings or the
temperature/thermal derating of components usually state
or imply a maximum operating and/or storage temperature
(whether junction or hot-spot) and various electrical values
based upon DC power conditions measured in a still ambi-
ent at 25°C. However, to determine whether this assump-
tion is true for specific components, you may have to ques-
tion the manufacturers’ engineering staffs.
The physical configuration of the test environment is often
not specified; this failing most affects low, short-leaded
components such as those in SMT because of unstated sig-
nificant factors such as the orientation of the component,
the printed board conductor configuration, the use (or non-
use) of sockets and the velocity of the airstream immedi-
ately adjacent to the component under test.
E-5.3 Failure Modes/Failure Mechanisms A failure
mode is the failure of a component to perform its electronic
or mechanical function. An electronic component fails due
to the underlying chemical, physical or mechanical mecha-
nisms.
For instance, an integrated circuit (IC) can fail due to an
open failure mode on a given pin or lead.
The responsible failure mechanisms can include: external
lead contamination leading to an open solder joint; lifted
bond wire at the internal package lead; corroded wire in the
package; resistive and brittle intermetallic compound
(IMC) growth at the wire/package interface; broken bond
wire (due to cyclic fatigue from external temperature
cycling, cyclic fatigue from internal power cycling, tensile
overload, material coefficient of thermal expansion incom-
patibles), melted bond wire (due to high currents); lifted
bond wire at the integrated circuit die (due to a poorly
executed bond, corroded bond pat metallization, contami-
nation on bond pad metallization, excessive IMC develop-
ment); open IC die metallization (due to poor oxide step
coverage, electrical overstress, electromigration, corrosion,
stress from dielectric layers, or stress from molding com-
pound movement). Note that these mechanisms can be the
result of simultaneous or sequential exposure of the com-
ponent to the physical/mechanical, chemical or electrical
stresses.
E-6.0 OVERVIEW OF STRESSES
E-6.1 Common Stresses and Component Response to
Stress
Thermal stresses include static high and low ambi-
ent temperature and cyclic ambient temperature; power
cycling results in cyclic internal temperatures. Cyclic tem-
peratures result in thermo-mechanical stresses. Electrical
stresses include static and cyclic power; static, cyclic and
transient voltage; current and current density; electrostatic
discharge (ESD) and electro-magnetic interference (EMI).
Chemical stresses include moisture or humidity, corrosive
IPC-D-279 July 1996
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