IPC-D-279 EN.pdf - 第96页
boron trioxide, B 2 O 3 into the silicone dioxide layer , form- ing a boro-phospho-silicate glass (BPSG). Corrosion and opens occur on IC bond pads where the MC is delaminated, particularly in the corners of the chips in…

which the bond wires are connected to complete the circuit
from the IC bond pads).
The adhesion of the MC to the leadframe can be enhanced
by topical application of coupling agents or adhesion pro-
moters such as hexamethyldisilazane. If the strength of the
MC is insufficient, this degradation process progresses to
internal cracks in the MC, generally starting at sharp edges
and corners of the various elements in the package. If the
strength of the MC is inadequate, the cracks can progress
in the worst case to emerge on the surface of the package.
In milder cases, the cracks are internal and may terminate
on the lead fingers. ANSI/IPC-SM-786 illustrates these
progressive stages. Because stress concentration is known
to be very strongly dependent upon the radius at the edges
of the die attach paddle, a suggested crack reduction tech-
nique is to increase the radius at these edges.
Another result of moisture absorption by the plastic is an
apparent decrease in the glass transition temperature (Tg)
of the MC. This change in Tg means that the moist plastic
expands and contracts more with changes in temperature
due to soldering processes than when the package was ini-
tially manufactured. Because the CTE of the MC is much
higher than the CTE of the chip, substrate or leadframe, the
MC expands and contracts with respect to these other ele-
ments, introducing additional stress at the interface. This
stress, in the case of ICs, can result in bond pad cratering
and is additional to the stress caused by the initial IC pack-
age curing process. Moist PSMCs exposed to temperature
cycling demonstrate a rapid progressive delamination and
product failure; dry PSMCs exposed to the same T/C con-
ditions show very slow progressive delamination. The con-
clusion is that vulnerable PSMCs can be robust to delami-
nation under T/C if kept dry.
F-6.1 Shorts and Resistive Shorts in PSMCs
In common with through hole (TH) components, PSMCs
suffer from metallic dendrites between the lead fingers and
between leads. Dendrites are very thin, fragile metal
‘‘branches’’ which can be destroyed by casual contact or by
currents on the order of several hundred microamperes.
Dendrites form on surfaces and in cavities when the fol-
lowing conditions are present: continuous liquid water film
thicker than several molecules; hydrolyzable, ionizable
contaminant, particularly halides and acids, typically from
solder flux but may also be extracted from the MC by the
diffusing moisture; metallic conductors, particularly silver,
copper, lead and tin (where halides are present, gold will
also dendrite); electrical DC bias at low current levels
between the conductors. See also IPC-TR-476A.
Liquid water films occur in the package (or on the printed
board surface) when: the ambient humidity (relative
humidity) is high; the exposure duration is sufficient to
saturate the package (weeks to months at 25-35°C); there
is delamination, cracking or voiding in the package due to
initial manufacturing conditions or subsequent assembly
operations; there is power dissipated in the package insuf-
ficient to keep the water in the vapor state.
Where the ambient temperature is suddenly reduced, we
would expect that internal moisture vapor will condense at
the interfacial voids. When cold parts are exposed to a
humid environment, we expect superficial condensation.
Dendrites have been observed to be a result of: polyimide
film delamination from the MC; voids in the MC due to
improper material handling or due to improper process
parameters during the molding process; cracks between
lead fingers due to mechanical stresses applied during IC
manufacturing processes such as trim/form and thermal
shock stresses applied during IC manufacturing processes
such as solder dip; cracks between lead fingers due to
printed board assembly processes such as TH insertion and
SM pick-and-place; delamination along lead fingers and
leads which extend to the external surface of the package.
Cratering in silicone or GaAs ICs shows up under bonding
pads as cracks due to stresses introduced by the wire bond-
ing process. Cracks can grow during thermal shocks and
temperature cycling, allow metals such as aluminum to
move from the pad to the underlying semiconductor mate-
rial, and are manifested as a resistive short from the bond-
pad to or through the underlying junction.
F-6.2 Opens and Intermittent Opens in PSMCs
Opens have been traced to wirebreaks where the MC is
cracked, whether the crack originates from the chip, die
attach paddle, or lead finger.
Predictions by finite element analysis and data from pack-
aging stress test chips indicate the highest molding and
thermo-mechanical stresses will occur at the corners of ICs
and substrates.
Opens in metal conductors have been traced to stressed
metal patterns (thin film cracking or TFC) in the corner of
IC chips. Experiments with planarized passivation/metal
patterns show metal damage when delamination is NOT
seen. Experiments with non-planarized patterns show metal
damage when delamination IS seen. Planarization of the
passivation/metal patterns was introduced in ICs to mini-
mize stresses transmitted to the patterns by the initial mold-
ing process. Minimized stresses are also the focus of the
‘‘low stress’’ holding compound formulations.
Corrosion and open metal conductors occur on IC chip
surfaces when the passivation is stressed and ruptured and
the package experiences the conditions described under
‘‘dendrites.’’ Where the passivation structure includes a
phosphorous pentoxide, P
2
O
5
, rich silicon oxide layer, a
liquid water film can react with the P
2
O
5
, creating phos-
phoric acid, an excellent dissolver of the aluminum metal
conductors. This effect has been mitigated by incorporating
IPC-D-279 July 1996
84

boron trioxide, B
2
O
3
into the silicone dioxide layer, form-
ing a boro-phospho-silicate glass (BPSG).
Corrosion and opens occur on IC bond pads where the MC
is delaminated, particularly in the corners of the chips in
PSMC. Corrosion-related opens occur on any bondpads in
TH packages where delamination, cracking or MC voiding
has occurred, particularly on bonding pads associated with
centrally located lead fingers.
Intermittent opens have been observed in PSM, as well as
in PTH packages where the delamination or cracking
occurs at the tip of the lead finger, causing wedge bond lift
or wire break. Delamination can also occur at the ball
bond/pad site. The separation of the wedge bond from the
lead finger, the ball bond from the bond pad, or the broken
wire ends from each other are microscopic. The separation
may be very sensitive to changing temperature and is often
intermittent. The product may fail during temperature
ramps, but may be functional at the endpoint temperatures.
F-6.3 PSMC Delamination and Thermal Resistance
(
jc
Degradation)
Delamination and debonding of the die attach paddle/heat
spreader from the MC results in heat transfer by conduc-
tion through the gases in the voided region with an increase
in the θ
jc
. There is no data on the effect of various degrees
of delamination/ debonding on the magnitude of θ
jc
. Fur-
ther the increase in θ
jc
appears to be: greater for thinner
packages; greater for packages of thermally conductive
MC; expected to first appear in the corners of the die attach
paddle; more significant for the package surface where heat
is conducted to the printed board or to a heatsink by such
means as thermally conductive adhesive; more significant
for those components where heat dissipation or chip tem-
perature uniformity is critical and where variations in these
parameters affect performance or reliability.
F-7.0 RESISTORS
When resistors overheat or fail, the printed board under-
neath is often thermally degraded (with color changes in
the laminate or coatings as well as decreases in resistivity
of the laminate) or even charred, leading to catastrophic
failure and smoke. The pyrolytically generated gases may
or may not ignite. Printed board damage may be minimized
by placing a copper pad under the resistor; the additional
copper reduces the peak temperature experienced by the
printed board during overload of the resistor.
Above the critical value of resistance (where maximum
rated power is dissipated at maximum rated voltage), use
voltage derating rather than power derating.
Through-hole (TH) resistors are generally spaced apart
both because of their bulk and their need for PTH lands on
the substrate. Surface mount (SM) resistors can be
squeezed together because of their small size and because
of the small surface area required for lands on the sub-
strate. This opportunity for higher spatial density is rarely
refused by the designer; the result is higher power density
on the substrate.
TH and SM resistors dissipate their heat primarily through
their leads, which are both electrically and thermally con-
ductive, to the substrate conductors and thence to the air.
Because of the reduced solder land area on the SMT sub-
strate, the joint temperature will probably be higher in the
SMT version of a TH product.
TH resistors have a relatively large surface area available
to dissipate the heat to the air; in contrast, the active area
of the SM device is relatively small. Inexpensive TH resis-
tors are generally metal or carbon film. A relatively large
volume or mass of material is available to dissipate both
steady state and pulsating peak heat. Inexpensive SM resis-
tors are generally thick film in nature and printed on one
surface of a rectangular ceramic (generally alumina) body
of low thermal conductivity.
The SM active element has a very small thermal mass; the
active area of the SMT component can rapidly respond to
increased power input with increased active element tem-
peratures. Some resistor suppliers provide ratings on their
product performance as a function of duration of stress at
given temperatures and during assembly processing. SM
resistor power dissipation ratings should be approached
with caution; the data is generally obtained by the manu-
facturer in an undefined environment possibly described by
a single resistor and an environmental chamber with mov-
ing air of unspecified velocity. Thermal finite element
analysis (FEA) and IR scans are recommended for verifi-
cation of hot spot location and magnitude. The presence of
multiple heat dissipating elements in close proximity
reduces the power dissipation allowable for any given ele-
ment. No SM resistor manufacturer has provided allowable
active film or component surface temperature data.
F-7.1 A Checklist for Power Resistors
• Locate resistors for favorable convection cooling.
• Provide mechanical clamping or thermoset heat trans-
fer material to improve conductive heat transfer from
power resistors to heat sink or chassis.
• Use short leads whenever possible so that traces and
leads provide sufficient ‘‘heat dissipation’’ capability-
unless physical distance from the printed board is
required to minimize heat rise in the printed board.
• Individual power resistors over 10 cm long mounted
with axis horizontal to minimize hotspots along length;
average temperature of vertical and horizontal
mounted resistors is about the same.
• Groups of power resistors mounted with axes vertical.
Stagger resistors horizontally so that they don’t direct
hot airflows to their vertical neighbor.
July 1996 IPC-D-279
85

• Design for a patch of copper foil beneath the body of
axial power > 2 Watts resistors to minimize charring of
the printed circuit board during fault conditions.
• At very high surface temperatures, radiation effects
can be significant.
F-7.2 Trimmed Resistors The resistance value of rectan-
gular or cylindrical, thick-film or thin-film resistors is
adjusted by laser thermal ablation, sandblasting or abra-
sion. On cylindrical film resistors, high speed spiral grind-
ing or abrasion is also used to adjust the resistance value.
On some rectangular thin metal-film resistors, controlled
oxidation of the metal is used to adjust the resistance value.
The mechanical abrasion or thermal ablation resistance
value adjustment processes leave a narrow kerf. The kerf,
if bridged by conductive materials such as flux, can be the
site of surface leakage. The kerf can also be the site of
voltage-induced breakdown, depending on the kerf geom-
etry. See also voltage stress and moist environment notes.
Note that the kerf on a TH Axial resistor which has been
trimmed to value is generally quite long compared to the
kerf on a rectangular SM device; hence the potential across
the kerf of the TH component is lower (less stress) than
that across the kerf of the SM component. In general, the
kerf is mechanically protected from the environment by a
plastic conformal coating. The kerf of any trimmed resistor
is best protected by a glass or inorganic coating which
covers the resistive and conductive areas; under conditions
of severe thermal or mechanical stress, even the inorganic
protective glaze can chip, crack or craze, leading to corro-
sion and failure of the resistive film or termination.
F-7.3 Fixed Resistors Use metal oxide above 1 Watt or
wire-wound resistors above 2 Watts.
SM Metal Electrode Face bonded (MELFs) configuration
components may require special ‘‘U−’’ shaped land pat-
terns to reduce rolling or may require adhesive to retain
position during reflow.
F-7.3.1 Metal Film Resistors Use for high stability, long
life, high frequency, reliability and accuracy.
Metal-film resistors perform better in applications requiring
precision and stability compared to wire-wound resistors
according to warranty data.
Specific Cautions: Humidity or salt air can cause shunt
paths on surface of resistor and shorting between spirals.
Opens can be caused by mechanical damage. Higher noise
than wire-wound. Spiral cut: Opens may occasionally
occur due to too thin a resistance track due to non-uniform
resistance spiral. Operation at RF above 100 MHz may
produce inductive effects. Shorts may occasionally occur
due to protuberances on adjacent resistance spiral. Opera-
tion at > 400 MHz results in reduced effective resistance
due to dielectric effects. Critical matched resistors should
be purchased and installed as a set. Resistive film can cor-
rode if encapsulant or conformal coating is breached; a
common point of entry for water or conductive contamina-
tion is the juncture of the terminal and overmoulding mate-
rial or conformal coating. Mechanical stresses affect this
type at temperatures < − 55°C.
Metal films of nickel-chrome (NiCr) alloy (aluminum
doped) are susceptible to corrosion when exposed to halide
compounds such as chloride-bearing fluxes if there is dam-
age to the coating during component manufacture or
printed board assembly, and subsequent exposure of the
component to corrosive materials and moisture. The alumi-
num dopant is very sensitive to basic or halide solutions
such as fluxes and saponifiers; the presence of this dopant
should be identified for ease of failure analysis. This cau-
tion applies to TH as well as SM thin-film resistors, both
epoxy coated and bare. Require your supplier of nickel-
chromium (nichrome) resistors to identify use of alu-
minium as an alloying agent.
Small thin-film resistors of high value (> 100 kΩ) are the
most susceptible to moisture.
F-7.3.2 Thick-Film Resistor Networks Good tracking
between components on the same substrate.
Resistive film can corrode if encapsulant or conformal
coating is breached. Mechanical stresses affect this type at
temperatures < −55°C.
F-7.3.3 Metal Oxide Film Resistors Resistive film can
corrode if encapsulant or conformal coating is breached.
Mechanical stresses affect this type at temperatures less
than −55°C.
F-7.3.4 Resistor Chips
Caution
General purpose SM resistors are generally thick-film cer-
met on ceramic substrate. Note the ESD sensitivity of bare
films and metallic thin films over thin oxides. See also the
comments on trimmed film resistors.
The reduced component lead surface area of SM resistors
results in higher thermal resistance from resistive film to
air. The smaller component and layout areas can result in
higher power densities and hence higher resistive element
temperatures. The smaller heat dissipation areas can result
in higher solder joint and substrate temperatures. Avoid
resistors that have been trimmed more than 50% of value.
Opens occur in the SM ceramic component body due to
damage from mechanical stresses such as overload from
vibration, shock or flexure of the PWA during service life.
Opens occur in the SM ceramic component body and in the
body-to-termination interface due to damage from
IPC-D-279 July 1996
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